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Ohio project takes biofuel production on the road

This mobile biofuel refinery solves supply chain problems by traveling directly to where feedstock can be obtained. (Photo courtesy Battelle)

This mobile biofuel refinery solves supply chain problems by traveling directly to where feedstock can be obtained. (Photo courtesy Battelle)

©2014 E&E Publishing, LLC
Republished with permission

By Amanda Peterka

Companies aspiring to produce next-generation biofuels struggle to get raw material to production plants.

Collecting biomass — crop residues, tree trimmings and grasses — requires a sprawling rural network of landowners, truckers and storage facilities, a complicated and expensive proposition.

So research-and-development nonprofit Battelle Memorial Institute is trying to take the production plant to the biomass field on the back of an 18-wheel tractor-trailer.

“The idea is that you have biomass that are in potentially remote locations that have low energy densities, are bulky and would be expensive to ship elsewhere,” said Mark Perry, program manager at Battelle Biofuels and Bioproducts. “So if you could take the unit to a biomass source, you could create a high-energy density bio-oil liquid from that, which would then be further upgraded to another product.”

Battelle has a pilot project at its headquarters in Columbus, Ohio, where a worker — usually Perry — feeds shovels of sawdust, pine chips and grass into the hopper right on site. The raw materials are fed into a reactor where a high-temperature process known as catalytic pyrolysis takes place; oil comes out the other end and can be shipped to refineries for use in either fuels or chemicals.

If it works, the model could pay off for Battelle, a top federal contractor and an operator of several national laboratories. The project could spare Battelle the $200 million cost of building a massive production facility. Battelle’s goal is to deploy many smaller units at about 10 percent the scale and cost of commercial-scale biorefineries.

“You’re not going to have a huge capital investment in these because these are going to be standard unit operations that will be manufactured in a factory, put on a truck and rolled out,” said Dan Anderson, a senior project manager at the Pacific Northwest National Laboratory, which is operated by Battelle.

Nor will the company have to spend much on transporting raw material to such a facility.

“It’s easier to transport 100 gallons of oil than 1 ton of wood, so it’s easier to have that processing step in the field. I think they [Battelle] will have some interesting cost advantages,” said Andrew Soare, a renewable fuels analyst at Lux Research. “That said, they have to prove that they can get yields and process efficiency. They’ll definitely miss out on some economies of scale.”

Battelle is first eyeing the chemicals market, followed by biofuels, Perry said. It is working to produce a drop-in biofuel, or a fuel that can be used directly in existing infrastructure instead of being blended in small amounts into petroleum — unlike conventional ethanol, which corrodes pipelines.

The company is planning to spin out a separate firm this year to develop the idea. It’s currently defining the business strategy.

The greatest potential may be in the Southeast, which is far from existing ethanol infrastructure and is amenable to different types of trees that can be used to make biofuels.

Battelle is looking at “what are the economics, how far away are the bio-oil producing machines from the hub so that it still remains economical,” Perry said. “You balance that with the capital cost and the operating costs of upgrading the reactors.”

Battelle began with a lab-scale unit about the size of a refrigerator. The company’s current pilot-scale model can convert 1 ton of biomass into 130 gallons of crude bio-oil a day.

There are few precedents for the Battelle projects.

According to media reports, North Korea is running trucks retrofitted with wood gasifiers, units on the bed of the truck that can convert timber or charcoal to a synthetic gas out in the field. And American biofuels company Sweetwater Energy is experimenting with converting plant materials to sugars in several satellite hubs and then transferring the sugars, rather than the biomass itself, to a central hub to ferment into ethanol.

And Utah State University researcher Foster Agblevor has developed a mobile pyrolysis unit that converts poultry litter into bio-oil.

“You just drive the unit to a farm, collect the poultry litter and pyrolize it,” said Agblevor, who did his initial work on the unit at Virginia Tech University. “The same concept can be applied to woody biomass where there’s a high concentration of feedstock.”

Low energy content

Battelle’s technology of choice is also catalytic pyrolysis, a thermochemical reaction devoid of oxygen that can take in a broad range of raw materials. In the process, inputs are heated to around 500 degrees Celsius. The resulting vapor is further treated and rapidly cooled down, producing a crude bio-oil. Biochar produced as a byproduct can be sold as a soil fertilizer or returned to the process to generate the heat needed to get to 500 degrees C.

But though researchers see big potential in thermochemical techniques, there are still technological barriers to bringing pyrolysis oil up to commercial scale.

“For pyrolysis, there’s often a refining step needed to go from pyrolysis oil into your fuel. That’s one of the challenges because that can be expensive,” Soare said. “You have to either build a separate refining facility or sell it to a refiner.”

The main problem with pyrolysis is that it produces oil that’s about 40 percent oxygen and packs less energy than petroleum.

“The barrier has always been the poor stability of pyrolysis oils,” Agblevor said. “The problem is that, biomass in general — they have a lot of oxygen. If you compare biomass to petroleum, petroleum has very little oxygen. Coal has very little oxygen. Biomass has a ton of oxygen. Because of the oxygen content, the energy content is low.”

Battelle researchers and their collaborators have developed catalysts to use in the pyrolysis process that lower the amount of oxygen in the resulting oil. The goal is to get the oxygen content as near to zero as possible, said Anderson of the Pacific Northwest National Laboratory, who has been involved with Battelle’s project since 2009.

Researchers are still working on perfecting a catalyst that can regenerate itself and be effectively used on the small scales that Battelle is targeting.

“I think that we’re talking about a couple of years to perfect the catalyst part of the technology,” Anderson said.

The fuel produced through Battelle’s process already meets U.S. EPA’s standards under the renewable fuel standard, meaning refiners can use it to comply with their annual targets for advanced biofuel use.

Perry said it was too early in the process to lay out a timeline for when mobile units producing oil may become a common sight in rural areas.

He said he has more immediate concerns: “We need a name for our company.”

Comments (1)

Excellent new approach to bio-mass oil. Here in Europe, the Austrian town of Guessing, near the Hungarian border, developed a pyrollysis plant- that uses woody mass from the extensive, surrounding paper pulp forestry operations that works in two ways- 1, it anaerbically incinerates the wood to produce – carbon-monoxide and soot – and cleanly incinerates that in a snall GaS, gas and steam combined cycle system burning at 60% efficiencies- with district heat feeding local factories around it- (hardwood parket manufactures deliberately settled near the plant. Excess gas is fed into a a catalytic pyrolysis “Fischer-Tropsch” system- (used during WW II to cnvert coal to gasoline and diesel-) for higher oxygen content “bio-diesel” which burns very nicely in today´s t.d.i. diesels. when the fuel is pre-heated by running the fuel line- through a chamber filled with hot cooling water. Despite the higher oxygen content, today´s microwaved air intake, T.D.I. diesels burn it vvery easilly. And like Diesel, it can be heat emulsified with electrocatallytically – nano-tube demineralized water- for a ten percent water content, and a anothere 5% rape seed oil is added. The Austrian, German, Slovenian, Czech goal is to get these units up in every county – for combined heat-power, at 95% efficiencies plus bio-diesel.
There is another approach developed by the Max Planck Institute at Potsdam by Prof. Antionetti. The cellulose bio mass is placed in a “pressure cooker” along with a certain cheap mineral catalyst, and inside a day, it “recarbonizes to brown coal” which can then go into advanced Fischer-Tropsch. 1 cubic meter of pulp bio-mass poduces about 200 liters of bio-fuel that way. (50 imperial gallons)
Farms in the Guessing Austria region also installed 1 and 2 phase manue methane digesters for combined heat and power generation. The next development there is using the remaining, partically dehydrated cow and pig manure- as a bio-fuel source as well. That entails using wind energy to generate hydrogen at a rate of 600 liters gas per input kilowatt hour, hydrogenating the cow manure, adding – the same catalyst as used in the Antionetti “re-caronisation process”- and putting it into a pressure cooker process for a day. It comes out as light bio-crude.
That is, manure is a dual source of fuel, 1st for bio-methane, and then, as “wind syn-gas” hydrogenated- bio-oil which also burns nicely in diesels with similarlight modifications for running all farm equipment. All three bio-gas, bio-fuel options will be built out in Germany, Austria and Switzerland.

By Kent Otho Doering on Jan 23, 2014